869541-51-5

Basic information

• Product Name: (S)-1-(2-propenyl)-2-iodo-2-cyclohexenol
• Synonyms: (S)-1-(2-propenyl)-2-iodo-2-cyclohexenol
• CAS NO: 869541-51-5
• Molecular Weight: 264.106
• Mol File: 869541-51-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-1-(2-propenyl)-2-iodo-2-cyclohexenol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-(2-propenyl)-2-iodo-2-cyclohexenol(869541-51-5)
• EPA Substance Registry System: (S)-1-(2-propenyl)-2-iodo-2-cyclohexenol(869541-51-5)

Safety Data

• Hazardous Substances Data: 869541-51-5(Hazardous Substances Data)

Upstream product

• 33948-36-6 2-iodocyclohex-2-en-1-one 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 54655-41-3 B-allyl-1,3,2-dioxaborinane 

Relevant articles and documents

Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and α-Ketoesters

A set of broadly applicable methods for efficient catalytic additions of easy-to-handle allyl-B(pin) (pin=pinacolato) compounds to ketones and acyclic α-ketoesters was developed. Accordingly, a large array of tertiary alcohols can be obtained in 60 to >98 % yield and up to 99:1 enantiomeric ratio. At the heart of this development is rational alteration of the structures of the small-molecule aminophenol-based catalysts. Notably, with ketones, increasing the size of a catalyst moiety (tBu to SiPh3) results in much higher enantioselectivity. With α-ketoesters, on the other hand, not only does the opposite hold true, since Me substitution leads to substantially higher enantioselectivity, but the sense of the selectivity is reversed as well.