86960-02-3

Basic information

• Product Name: 5-propyl-5-hydroxy-3-phenyl[5]ferrocenophane-1-one
• CAS NO: 86960-02-3
• Molecular Weight: 402.316
• Mol File: 86960-02-3.mol

Chemical Properties

• CAS DataBase Reference: 5-propyl-5-hydroxy-3-phenyl[5]ferrocenophane-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-propyl-5-hydroxy-3-phenyl[5]ferrocenophane-1-one(86960-02-3)
• EPA Substance Registry System: 5-propyl-5-hydroxy-3-phenyl[5]ferrocenophane-1-one(86960-02-3)

Safety Data

• Hazardous Substances Data: 86960-02-3(Hazardous Substances Data)

Upstream product

• 32985-99-2 3-phenyl[5]ferrocenophane-1,5-dione 
• 10557-57-0 propylmagnesium iodide 

Relevant articles and documents

STEREOCHEMISTRY OF THE REACTION OF GRIGNARD REAGENTS WITH 3-ARYL- AND 3-ALKYL-FERROCENOPHANE-1,5-DIONES

The reaction of Grignard reagents with 3-aryl- and 3-alkyl-ferrocenophane-1,5-diones is completely stereospecific giving exclusively derivatives in which the introduced alkyl groups are cis to substituents at C(3).The chair conformation, with strong intramolecular hydrogen bonding, predominates in the hydroxyketones obtained, and this is the only conformer present in the case of the dihydroxy derivatives.The second isomer of the hydroxyketones is also the cis type, but its bridge has a twist conformation.