86962-22-3Relevant academic research and scientific papers
Preferential carbene insertion into Ge-H vs. other heavier group 14 hydrides via samarium carbenoids
Kondo, Hitoshi,Yamanoi, Yoshinori,Nishihara, Hiroshi
, p. 6671 - 6673 (2011/08/02)
The relative reactivities of Zn, Al, and Sm carbenoids in the chemoselective carbene insertion reaction of heavier group 14 hydrides were studied. By variation of the reaction protocols using Sm carbenoids, insertion reaction can favour the Ge-H bonds to give Ge-alkylated derivatives in good to high yield.
METHYLPHENYLTRIPHENYLGERMYLSILANES FONCTIONNELS OPTIQUEMENT ACTIFS. II. REACTIONS DE CLIVAGE DE LA LIAISON Si-Ge
Corriu, R. J. P.,Ould-Kada, S.,Lanneau, G. F.
, p. 39 - 50 (2007/10/02)
The cleavage of a silicon-germanium bond in the presence of organometallics has been studied on the optically active compounds MePh(X)SiGePh3 (X=H, OMe).Depending on the nature of the nucleophile, we obtained mixed products, corresponding to the formation of Ph3Ge-, transient radical-anions, or catalytic reactions.
