86964-84-3

Upstream product

• 86975-62-4 Benzoic acid (3aS,4R,5R,7S,7aS)-7-amino-2,2-dimethyl-4-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-hexahydro-benzo[1,3]dioxol-5-ylmethyl ester 
• 74766-86-2 DL-3,4-di-O-Acetyl-1,2-anhydro-(1,2,3/4)-5-benzoyloxymethyl-5-cyclohexene-1,2,3,4-tetrol 
• 108-24-7 acetic anhydride 
• 86964-83-2 C₅₁H₆₁NO₂₂ 

Downstream Products

• 37248-47-8 (2R,3R,4S,5S,6R)-2-[(1R,2R,3S,4S,6R)-2,3-Dihydroxy-6-hydroxymethyl-4-((1R,4S,5R,6S)-4,5,6-trihydroxy-3-hydroxymethyl-cyclohex-2-enylamino)-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 87037-90-9 (2R,3R,4S,5S,6R)-2-[(1R,2R,3S,4S,6R)-2,3-Dihydroxy-6-hydroxymethyl-4-((1S,4R,5S,6R)-4,5,6-trihydroxy-3-hydroxymethyl-cyclohex-2-enylamino)-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 

Relevant academic research and scientific papers

A TOTAL SYNTHESIS OF 6"-EPIVALIDAMYCIN A AND ITS DIASTEREOMER

A total synthesis of the 6"-epimer of validamycin A and its diastereomer has been accomplished by a coupling reaction of the racemic peracyl 5,6-dihydroxy-1-hydroxymethyl-1,3-cyclohexadiene monoepoxide, the precursor of the unsaturated branched-chain cyclitol portion, with the protected β-D-glucopyranosylvalidamine, followed by acid hydrolysis and O-deacylation.