869660-97-9

Upstream product

• 346588-20-3 1-O-benzyl-2,3-O-(1-methylethylidene)-D-arabinitol 
• 3969-59-3 mannitol triacetonide 
• 13039-93-5 2,2:4,5-di-O-isopropylidene-D-arabinose 
• 19139-73-2 (4S,4’R,5R)-5-[(benzyloxy)methyl]-2,2,2’,2’-tetramethyl-4,4’-bis[1,3-dioxolane] 
• 19139-74-3 2,3:4,5-di-O-isopropylidene-D-arabinitol 
• 869660-96-8 (2R,3R,4R)-1-O-benzyl-2,3-O-isopropylidene-5-(4-methoxyphenyl)pentane-1,2,3,4-tetrol 
• 869660-95-7 1-O-benzyl-2,3-O-isopropylidene-4-oxiranyl-D-arabinitol 

Downstream Products

• 869660-99-1 (2R,3R,4S)-4-(tert-butoxycarbonyl)amino-2,3-O-isopropylidene-5-(4-methoxyphenyl)pentane-1,2,3-triol 
• 1053622-69-7 Methanesulfonic acid (4R,5R)-5-[(S)-1-tert-butoxycarbonylamino-2-(4-methoxy-phenyl)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester 
• 869660-98-0 (2R,3R,4S)-1-O-benzyl-4-(tert-butoxycarbonyl)amino-2,3-O-isopropylidene-5-(4-methoxyphenyl)pentane-1,2,3-triol 
• 19713-95-2 (2S,3R,4R)-3,4-dihydroxy-2-(4-methoxybenzyl)pyrrolidine 
• 111765-92-5 (2S,3R,4R)-N-(benzyloxycarbonyl)-3,4-dihydroxy-2-(4-methoxybenzyl)pyrrolidine 

Relevant academic research and scientific papers

A new approach to (+)-anisomycin

An efficient approach to enantiomerically pure (+)-deacetylanisomycin 2a and a formal synthesis of (+)-anisomycin 2 (11% overall yield in 10 steps) have been achieved through simple and good yielding reactions, starting from 1,2:3,4:5,6-tri-O-isopropylidene-D-mannitol 3. Grignard reaction and intramolecular cyclisation reactions are key steps in the strategy.