86970-88-9Relevant academic research and scientific papers
Lead Tetra-acetate-mediated Oxidative Cyclizations of Isoquinoline Alkyl Substituted Methylene Urethanes (Enamides) to Isoquinoline Hydroxyoxazolidinones.
Lenz, George R.
, p. 33 - 38 (2007/10/02)
Oxidation of disubstituted 1-methylene-tetrahydroisoquinoline-2-carboxylates with lead tetra-acetate (LTA) causes a rapid oxidative cyclization to an isoquinoline hydroxyoxazolidinone.The products possess acyliminium character and the hydroxy group is rea
A NEW GENERATION OF α-OXA-ACYLIMINIUM IONS AND AN APPLICATION TO A SYNTHESIS OF OXAZOLOISOQUINOLINE AND RELATED COMPOUNDS
Kano, Shinzo,Yuasa, Yoko,Yokomatsu, Tsutomu,Shibuya, Shiroshi
, p. 1475 - 1476 (2007/10/02)
The carbamates, obtained by the reaction of the azide with ethyl glycolate and ethyl lactate, were reduced with i-Bu2AlH and the reduction products were treated with formic acid to give the corresponding oxazoloisoquinolines.By this method, the thi
