86981-91-1Relevant academic research and scientific papers
Formation of trisubstituted buta-1,3-dienes and α,β-unsaturated ketonesviathe reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents
Dvo?áková, Hana,Koudelka, Jakub,Oeser, Petr,Tobrman, Tomá?
, p. 35109 - 35120 (2020)
We studied the reactions of vinyl phosphates and vinyl phosphordiamidates containing an ester functional group with organometallic reagents. We found that the functionalized vinyl phosphates were smoothly converted into tri- and tetrasubstituted buta-1,3-
A CONVENIENT ROUTE TO α,β-UNSATURATED METHYL KETONES APPLICATION TO RETINAL ANALOGUE SYNTHESIS
Croteau, Allan A.,Termini, John
, p. 2481 - 2484 (2007/10/02)
Deprotonated ketimines 1a,b add to aldehydes and ketones to provide tri- and tetra-substituted α,β-unsaturated methyl ketones 2a,b with substantial percentage of Z-geometry which are not readily accessible by other methods.
