86990-75-2Relevant academic research and scientific papers
The Synthesis and Selected Chemistry of 6-Alkyl-6-carbalkoxy- and 6-Alkyl-6-(aminocarbonyl)-2,4-cyclohexadien-1-ones and Cyclohexadienone Ketals
Schultz, Arthur G.,Dittami, James P.,Lavieri, Frank P.,Salowey, Christina,Sundararaman, Padmanabhan,Szymula, Mary Beth
, p. 4429 - 4440 (2007/10/02)
The preparation of several 6-alkyl-6-carbalkoxy-2,4-cyclohexadien-1-ones and corresponding C(1) ketals is described.Birch reduction-alkylation of methyl 2-methoxybenzoates gives 6-alkyl-6-carbomethoxy-1-methoxy-1,4-cyclohexadienes 4a-e and 5a-d, and these
SYNTHESIS OF 6-ALKYL-6-METHOXYCARBONYL-2,4-CYCLOHEXADIEN-1-ONES AND CYCLOHEXADIENONE KETALS
Schultz, Arthur G.,Dittami, James P.
, p. 1369 - 1372 (2007/10/02)
The title compouds are readily available by reductive-alkylation of o-methoxybenzoic acid esters followed by a bromination-dehydrobromination sequence.
