86992-09-8

Basic information

• Product Name: bis(maleic anhydride)triphenylphosphinetricarbonylmolybdenum⁽⁰⁾
• CAS NO: 86992-09-8
• Molecular Weight: 638.378
• Mol File: 86992-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(maleic anhydride)triphenylphosphinetricarbonylmolybdenum⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: bis(maleic anhydride)triphenylphosphinetricarbonylmolybdenum⁽⁰⁾(86992-09-8)
• EPA Substance Registry System: bis(maleic anhydride)triphenylphosphinetricarbonylmolybdenum⁽⁰⁾(86992-09-8)

Safety Data

• Hazardous Substances Data: 86992-09-8(Hazardous Substances Data)

Upstream product

• 108-31-6 maleic anhydride 
• 14971-42-7 triphenylphosphinemolybdenumpentacarbonyl 

Relevant articles and documents

Maleic Anhydride Complexes of Chromium(0) and Molybdenum(0) Carbonyls

Maleic anhydride reacts with LM(CO)5 (M = Cr, L = tetraazaadamantane (taad), morpholine and piperidine; M = Mo, L = taad, butyl amine, cyclohexyl amine, pyridine, morpholine, triphenylphosphine and piperidine to give bis(maleic anhydride)-aminetricarbonylmetals(0).Similar reactions with (L-L)Mo(CO)4 (L-L = o-phen and 2,2'-bipyridine) yield (L-L)(maleic anhydride)Mo(CO)3*ArCr(CO)3 (Ar = benzene, toluene, o- and p-xylene) under UV irradiation react with a benzene solution of maleic anhydride to give Ar(maleic anhydride)Cr(CO)2.IR spectra of the complexes show that maleic anhydride bonds to the metal atoms via C=C.