870135-79-8

Upstream product

• 917-54-4 methyllithium 
• 870135-78-7 (4aR,6S,7S,8R,8aR)-6-Allyl-8-benzyloxy-2,2-di-tert-butyl-hexahydro-1,3,5-trioxa-2-sila-naphthalen-7-ol 

Downstream Products

• 870135-80-1 (2S,3S,4S,5R,6R)-2-Allyl-4-benzyloxy-6-hydroxymethyl-3-methyl-tetrahydro-pyran-3,5-diol 
• 1092964-98-1 C₂₇H₄₂O₅Si 
• 870135-86-7 3-[(2R,3S,4aR,5aS,6aR,8S,10aS,11aS,12S,12aR)-12-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-8-methoxy-11a-methyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-2-yl]-propan-1-ol 
• 870135-92-5 (2R,3S,4aR,6R,7S,8aS,9S,9aR,10aS)-2,7-Diallyl-9-benzyloxy-3,8a-dimethyl-6-pent-4-enyloxy-3-vinyloxy-decahydro-1,8,10-trioxa-anthracene 
• 870135-91-4 (2R,3S,4aR,6R,7S,8aS,9S,9aR,10aS)-2,7-Diallyl-9-benzyloxy-3,8a-dimethyl-6-pent-4-enyloxy-decahydro-1,8,10-trioxa-anthracen-3-ol 
• 870135-89-0 (2R,3S,4aR,6R,7S,8aS,9S,9aR,10aS)-2-Allyl-9-benzyloxy-7-(3-hydroxy-propyl)-3,8a-dimethyl-decahydro-1,8,10-trioxa-anthracene-3,6-diol 
• 870135-94-7 Trifluoro-methanesulfonic acid (2R,3R,4S,5S,6S)-6-allyl-4-benzyloxy-5-hydroxy-5-methyl-3-triethylsilanyloxy-tetrahydro-pyran-2-ylmethyl ester 
• 870135-88-9 (2R,3S,4aR,5aS,6aR,8S,10aS,11aS,12S,12aR)-2-Allyl-12-benzyloxy-8-methoxy-3,11a-dimethyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-ol 
• 870135-87-8 (2R,3S,4aR,5aS,6aR,8S,10aS,11aS,12S,12aR)-2-Allyl-12-benzyloxy-8-methoxy-11a-methyl-tetradecahydro-1,5,7,11-tetraoxa-naphthacen-3-ol 
• 870135-90-3 (2R,3S,4aR,6R,7S,8aS,9S,9aR,10aS)-2,7-Diallyl-9-benzyloxy-3,8a-dimethyl-decahydro-1,8,10-trioxa-anthracene-3,6-diol 
• 870135-95-8 (2S,3S,4S,5R,6R)-2-Allyl-4-benzyloxy-3-methyl-6-(3-trimethylsilanyl-prop-2-ynyl)-tetrahydro-pyran-3,5-diol 

Relevant academic research and scientific papers

Harnessing glycal-epoxide rearrangements: The generation of the AB, EF, and IJ rings of adriatoxin

(Chemical Equation Presented) Climbing the ladder: The generation of three bicyclic subunits ofadriatoxin (see structure) was accomplished by using glycal-epoxide rearrangements, glycal-Claisen rearrangements, and C-glycoside-forming reactions.

Rapid two-directional synthesis of the F-J fragment of the gambieric acids by iterative double ring-closing metathesis

(Chemical Equation Presented) D-glucal is the starting point for the efficient synthesis of the F-J fragment of the gambieric acids (see scheme). The hiring diol was subjected to double two-directional alkynyl ether formation, carbocupration ring-closing