87030-51-1

Basic information

• Product Name: 3,6-Didesoxy-3,6-dihydrazino-muco-inosit
• CAS NO: 87030-51-1
• Molecular Weight: 208.217
• Mol File: 87030-51-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,6-Didesoxy-3,6-dihydrazino-muco-inosit(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-Didesoxy-3,6-dihydrazino-muco-inosit(87030-51-1)
• EPA Substance Registry System: 3,6-Didesoxy-3,6-dihydrazino-muco-inosit(87030-51-1)

Safety Data

• Hazardous Substances Data: 87030-51-1(Hazardous Substances Data)

Upstream product

• 50474-02-7 1,2:4,5-Dianhydro-cis-inosit 

Downstream Products

• 755690-05-2 (1α,2α,3β,4α,5α,6β)-3,6-Diamino-1,2,4,5-cyclohexantetrol 

Relevant articles and documents

Polyfunctionalised Cyclohexanes from Dianhydroinositols. cis-1,3(1,4)-Inosadiamines from Benzene

The preparative value of the dianhydroinositols 4 - 6, which are readily available from benzene, for the total synthesis of cis-1,4- and cis-1,3-disubstituted cyclohexanetetrols is demonstrated.With monovalent reagents (H2O, HI, NaN3, NH2NH2) the twofold epoxide opening proceeds regioselectively (1,4-disubstitution) yielding the muco- and chiro-cyclohexane derivatives 9, 17, and 26.With hydrazine and N,N'-dimethylhydrazine as 1,2-dinucleophiles the cis-1,3-inosadiamines 7 g (5-epistreptamine) and 16 g, j (2-epistreptamine, actinamine) are obtained from 4/5 in good yields (75 - 90percent).From the less symmetrical 6, however, only the mixture of 25 g (streptamine) and 27 g is produced in modest yield (ca. 50percent).The epoxide opening reactions starting from 4 - 6 are kinetically so similar that a selective opening is not possible.