87036-30-4

Basic information

• Product Name: cobalt(II)(4-NO₂INAP)2*4-NO₂HINAP
• CAS NO: 87036-30-4
• Molecular Weight: 639.417
• Mol File: 87036-30-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cobalt(II)(4-NO₂INAP)2*4-NO₂HINAP(CAS DataBase Reference)
• NIST Chemistry Reference: cobalt(II)(4-NO₂INAP)2*4-NO₂HINAP(87036-30-4)
• EPA Substance Registry System: cobalt(II)(4-NO₂INAP)2*4-NO₂HINAP(87036-30-4)

Safety Data

• Hazardous Substances Data: 87036-30-4(Hazardous Substances Data)

Upstream product

• 6147-53-1 cobalt(II) diacetate tetrahydrate 

Relevant articles and documents

Bis- and Tris-chelates of Cobalt with Some Isonitrosoacetophenones

Cobalt complexes of the type, ML2.nH2O , ML2.HL and ML3 have been prepared and characterized.The IR data suggest N- and O-bondings of the oximino group in one and the same molecule of the complex, the exception being 4-NO2 substituted complex where bonding occurs through isonitroso nitrogen only.Substitution in the phenyl ring of the complexes produces shifts in ν(C=O) which are related to the Hammett's substituents parameters.The magnetic moments observed for the cobalt(II) complexes, except that of 4-NO2 substituted complex, indicate distorted octahedral geometry.The PMR spectra of cobalt(III) chelates with 4-MeHINAP and 4-OMeHINAP suggest a cis octahedral structure for these complexes.