87046-29-5Relevant academic research and scientific papers
THE CHEMISTRY OF FULMINIC ACID REVISED
Sarlo, Francesco De,Guarna, Antonio,Brandi, Alberto,Goti, Andrea
, p. 5181 - 5186 (2007/10/02)
The availability of a new synthesis of fulminic acid by hydrolysis of trimethylsilanecarbonitrile oxide allowed a reinvestigation of the chemistry of the title compound.Thus, cycloadditions to olefinic and acetylenic dipolarophiles are improved with respect to previous results and the oligomerisation is proved to occur via the reactive species hydroxyiminoacetonitrile oxide 7 and hydroxyiminomethyl-hydroxyimino-acetonitrile oxide 8.The Z-configuration, found for the oxime groups in these intermediates, is maintained in their derivatives, under kinetic control.
SIMPLE IN SITU PREPARATION OF FULMINIC ACID
Sarlo, Francesco De,Brandi, Alberto,Guarna, Antonio,Goti, Andrea,Corezzi, Silvia
, p. 1815 - 1816 (2007/10/02)
Fulminic acid, generated in situ by hydrolysis of trimethylsilanecarbonitrile oxide, is employed in cycloaddition reactions.
