870461-36-2

Upstream product

• 870461-26-0 (3S,1'S,4''S)-2-benzyl-1'-[(tert-butyldimethylsiloxy)-(2'',2''-dimethyl-1'',3''-dioxolan-4''-yl)methyl]-4-[2'''-(trimethylsilyl)ethoxy]-3,6-dihydro-2H-1,2-oxazine 
• 870461-25-9 C₂₀H₃₃NO₄Si 

Downstream Products

• 874947-18-9 (1S,4R,5R,6S,10S)-7-benzyl-5-(tert-butyldimethylsilyloxy)-4-(tert-butyldimethylsilyloxy)methyl-2,2-dimethyl-3,8-dioxa-7-aza-bicyclo[4.3.1]decan-10-ol 

Relevant academic research and scientific papers

Synthesis of new enantiopure poly(hydroxy)aminooxepanes as building blocks for multivalent carbohydrate mimetics

New compounds with carbohydrate-similar structure (carbohydrate mimetics) are presented in this article. Starting from enantiopure nitrones and lithiated TMSE-allene we prepared three 1,2-oxazine derivatives which underwent a highly stereoselective Lewis

Synthesis of enantiopure carbohydrate mimetics by Lewis acid catalyzed rearrangement of 1,3-dioxolanyl-substituted 1,2-oxazines

(Chemical Equation Presented) Under control: Lewis acids induce an unexpected rearrangement of 1,3-dioxolanyl-substituted 1,2-oxazines to provide bicyclic compounds in a stereocontrolled manner. They are precursors for enantiopure carbohydrate mimetics co