87051-05-6

Basic information

• Product Name: C₁₄H₂₂O₄
• CAS NO: 87051-05-6
• Molecular Weight: 254.326
• Mol File: 87051-05-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₂O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₂O₄(87051-05-6)
• EPA Substance Registry System: C₁₄H₂₂O₄(87051-05-6)

Safety Data

• Hazardous Substances Data: 87051-05-6(Hazardous Substances Data)

Upstream product

• 72590-63-7 2-(methoxymethylene)adamantane 
• 75-07-0 acetaldehyde 

Relevant articles and documents

NEW CHEMISTRY OF ZWITTERIONIC PEROXIDES ARISING BY PHOTOOXYGENATION OF ENOL ETHERS

The rose bengal-sensitized photooxygenation of 2-methoxynorborn-2-ene (1) in acetaldehyde gave cis-1-carboxaldehyde-3-carbomethoxycyclopentane (31percent) and the cis and trans-Me derivatives of the cis-fused exo-1,2,4-trioxanes arising by addition of a molecule of oxygen and acetaldehyde to 1 at C3 and C2 respectively (13percent).Similar photooxygenation of 2-(methoxymetylidene)adamantane in the presence of acetaldehyde, propionaldehyde and pivalaldehyde gave adamantanone (31-42percent), and the cis and trans tricyclo3.7>decane-2-spiro-6'- in yields of 32-53percent.Trioxane formation under similar conditions was experienced for 1,1-di-t-butyl-2-methoxyethene and 2-(methylmercaptomethylidene)adamantane.The results are discussed in terms of an intermediate zwitterionic peroxide which can either close directly to a 1,2-dioxetane or, if aldehyde is present, condense across the CO function giving the 1,2,4-trioxane.