870542-52-2Relevant academic research and scientific papers
Solvent effects on oxygen atom transfer reaction between manganese(V)-oxo corrole and alkene
Yu, Lan,Wang, Qi,Dai, Lu,Li, Wei-Ying,Chen, Rong,Mahmood, Mian Hr,Liu, Hai-Yang,Chang, Chi-Kwong
, p. 447 - 449 (2013/07/27)
Pseudo-first order reaction rate constants of 5,10,15- tris(pentafluorophenyl)corrole Mn(V)-oxo (F15CMn(V)-oxo), 5,15-bis(pentafluorophenyl)-10-(phenyl)corrole Mn(V)-oxo (F10CMn(V)- oxo), 5,15-bis(phenyl)-10-(pentafluorophenyl)corrole Mn(V)-oxo (F 5CMn(V)-oxo) and 5,10,15-tris(phenyl)corrole Mn(V)-oxo (F 0CMn(V)-oxo) with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy. The results indicated that the oxygen atom transfer pathway between Mn(V)-oxo corrole and alkene is solvent-dependent.
