870892-55-0Relevant articles and documents
Inherently chiral uranyl-salophen macrocycles: Computer-aided design and resolution
Cort, Antonella Dalla,Mandolini, Luigi,Pasquini, Chiara,Schiaffino, Luca
, p. 9814 - 9821 (2005)
A flipping motion rapidly inverts the bent structure of uranyl-salophen compounds and, consequently, causes fast enantiomerization of nonsymmetrically substituted derivatives. This process has been previously slowed by introducing bulky substituents in th