87101-07-3

Upstream product

• 61250-65-5 dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) 
• 7175-47-5 4-methylphenyl isocyanide 
• 87101-16-4 Pt₂Cl₂(CH₃C₆H₄N(H)C)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*ClO₄^(1-)=(Pt₂Cl₂(CN(H)C₆H₄CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2)ClO₄ 

Downstream Products

• 87114-15-6 Pt₂I₂(CH₃C₆H₄N(CH₃)C)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*I^(1-)=(Pt₂I₂(CN(CH₃)C₆H₄CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2)I 
• 87101-17-5 Pt₂Cl₂(CH₃C₆H₄N(CH₃)C)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*I^(1-)=(Pt₂Cl₂(CN(CH₃)C₆H₄CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2)I 
• 87101-16-4 Pt₂Cl₂(CH₃C₆H₄N(H)C)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*ClO₄^(1-)=(Pt₂Cl₂(CN(H)C₆H₄CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2)ClO₄ 
• 87101-09-5 Pt₂Cl(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*PF₆^(1-)=(Pt₂Cl(CH₃C₆H₄NC)((C₆H₅)2PCH₂P(C₆H₅)2)2)PF₆ 

Relevant academic research and scientific papers

Binuclear isocyanide complexes of platinum(I). Facile N-protonation and alkylation of bridging isocyanide ligands to yield bridging aminocarbyne complexes

The platinum(I) dimers Pt2X2(μ-dppm)2 (X = Cl, I) react with p-tolyl isocyanide (CNR) under various conditions to give Pt2X2(μ-CNR)(μ-dppm)2, [Pt2X(CNR)(μ-dppm)2]+, [Pt2(CNR)2(μ-dppm)2]2+, and [Pt2(μ-CNR)(CNR)2(μ-dppm)2]2+. The complexes with bridging isocyanides undergo facile N-protonation and alkylation to yield the series of complexes [Pt2L2(μ-CNRR′)(μ-dppm)2] n+ (L = X, R′ = H, Me, n = 1; L = CNR, R′ = H, Me, n = 3). All structural assignments are made on the basis of vibrational, 1H NMR, and 31P NMR spectroscopy.