Cas 87114-16-7,Pt2(CH3C6H4N(H)C)(CH3C6H4NC)2((C6H5)2PCH2P(C6H5)2)2(3+)*3ClO4(1-)=(Pt2(CNHC6H4CH3)(CH3C6H4NC)2(C25H22P2)2)(ClO4)3

87114-16-7

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Product Name: Pt₂(CH₃C₆H₄N(H)C)(CH₃C₆H₄NC)2((C₆H₅)2PCH₂P(C₆H₅)2)2⁽³⁺⁾*3ClO₄^(1-)=(Pt₂(CNHC₆H₄CH₃)(CH₃C₆H₄NC)2(C₂₅H₂₂P₂)2)(ClO₄)3
Synonyms: Pt₂(CH₃C₆H₄N(H)C)(CH₃C₆H₄NC)2((C₆H₅)2PCH₂P(C₆H₅)2)2⁽³⁺⁾*3ClO₄^(1-)=(Pt₂(CNHC₆H₄CH₃)(CH₃C₆H₄NC)2(C₂₅H₂₂P₂)2)(ClO₄)3
CAS NO:87114-16-7
Molecular Formula:
Molecular Weight: 1809.76
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Pt₂(CH₃C₆H₄N(H)C)(CH₃C₆H₄NC)2((C₆H₅)2PCH₂P(C₆H₅)2)2⁽³⁺⁾*3ClO₄^(1-)=(Pt₂(CNHC₆H₄CH₃)(CH₃C₆H₄NC)2(C₂₅H₂₂P₂)2)(ClO₄)3(CAS DataBase Reference)
NIST Chemistry Reference: Pt₂(CH₃C₆H₄N(H)C)(CH₃C₆H₄NC)2((C₆H₅)2PCH₂P(C₆H₅)2)2⁽³⁺⁾*3ClO₄^(1-)=(Pt₂(CNHC₆H₄CH₃)(CH₃C₆H₄NC)2(C₂₅H₂₂P₂)2)(ClO₄)3(87114-16-7)
EPA Substance Registry System: Pt₂(CH₃C₆H₄N(H)C)(CH₃C₆H₄NC)2((C₆H₅)2PCH₂P(C₆H₅)2)2⁽³⁺⁾*3ClO₄^(1-)=(Pt₂(CNHC₆H₄CH₃)(CH₃C₆H₄NC)2(C₂₅H₂₂P₂)2)(ClO₄)3(87114-16-7)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 87114-16-7(Hazardous Substances Data)

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87114-16-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 87114-16-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,7,1,1 and 4 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 87114-16:
(7*8)+(6*7)+(5*1)+(4*1)+(3*4)+(2*1)+(1*6)=127
127 % 10 = 7
So 87114-16-7 is a valid CAS Registry Number.

87114-16-7Upstream product

87101-15-3 Pt₂(CH₃C₆H₄NC)(CH₃C₆H₄NC)2((C₆H₅)2PCH₂P(C₆H₅)2)2⁽²⁺⁾*2ClO₄^(1-)=(Pt₂(CH₃C₆H₄NC)3((C₆H₅)2PCH₂P(C₆H₅)2)2)(ClO₄)2

87114-16-7Downstream Products

87114-16-7Relevant academic research and scientific papers

Binuclear isocyanide complexes of platinum(I). Facile N-protonation and alkylation of bridging isocyanide ligands to yield bridging aminocarbyne complexes

Grundy, Kevin R.,Robertson, Katherine N.

, p. 1736 - 1742 (2008/10/08)

The platinum(I) dimers Pt2X2(μ-dppm)2 (X = Cl, I) react with p-tolyl isocyanide (CNR) under various conditions to give Pt2X2(μ-CNR)(μ-dppm)2, [Pt2X(CNR)(μ-dppm)2]+, [Pt2(CNR)2(μ-dppm)2]2+, and [Pt2(μ-CNR)(CNR)2(μ-dppm)2]2+. The complexes with bridging isocyanides undergo facile N-protonation and alkylation to yield the series of complexes [Pt2L2(μ-CNRR′)(μ-dppm)2] n+ (L = X, R′ = H, Me, n = 1; L = CNR, R′ = H, Me, n = 3). All structural assignments are made on the basis of vibrational, 1H NMR, and 31P NMR spectroscopy.

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