871320-45-5

Basic information

• Product Name: [bis(triphenylphosphoranylidene)ammonium][Mo(V)(benzene-1,2-dithiolato)3]
• CAS NO: 871320-45-5
• Molecular Weight: 1055.22
• Mol File: 871320-45-5.mol

Chemical Properties

• CAS DataBase Reference: [bis(triphenylphosphoranylidene)ammonium][Mo(V)(benzene-1,2-dithiolato)3](CAS DataBase Reference)
• NIST Chemistry Reference: [bis(triphenylphosphoranylidene)ammonium][Mo(V)(benzene-1,2-dithiolato)3](871320-45-5)
• EPA Substance Registry System: [bis(triphenylphosphoranylidene)ammonium][Mo(V)(benzene-1,2-dithiolato)3](871320-45-5)

Safety Data

• Hazardous Substances Data: 871320-45-5(Hazardous Substances Data)

Upstream product

• 21050-13-5 bis(triphenylphosphine)iminium chloride 

Relevant articles and documents

Synthesis and X-ray molecular structure of (PNP)2[Mo IV(C6H4S2-1,2)3] completing the structural characterization of the series [Mo(C6H 4S2-l,2)3]n-(n = 0, 1, 2)

The tris(benzene-1,2-dithiolato) complex (Li)2[Mo IV(C6H4S2-1,2)3] {(Li)2[MoIV(bdt)3]} (bdt2- = C 6H4S2-1,2 dianion) was synthesized from [MoCl4(CH3CN)2], (H2bdt), and nBuLi in THF. Complex (Li)2[MoIV(bdt)3] undergoes aerial oxidation to give Li[MoV(bdt)3]. Both complexes were crystallized from methanol as the salts (PNP)2[Mo IV(bdt)3] and (PNP)[MoV(bdt)3] {PNP+ = bis(triphenylphosphoranylidene)ammonium cation), and their molecular structures were determined by X-ray diffraction. The molybdenum(IV) complex [MoIV-(bdt)3]2- assumes a distorted trigonal prismatic coordination geometry (average twist angle φ = 24.8°) while the coordination geometry of [MoV(bdt)3] - is best described as distorted octahedral (average twist angle φ = 34.1°). Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.