87156-68-1Relevant academic research and scientific papers
Enabling bifunctionality and hemilability of N-heteroaryl NHC complexes
Specht, Zephen G.,Cortes-Llamas, Sara A.,Tran, Hai N.,Van Niekerk, Christoffel J.,Rancudo, Khing T.,Golen, James A.,Moore, Curtis E.,Rheingold, Arnold L.,Dwyer, Tammy J.,Grotjahn, Douglas B.
supporting information; experimental part, p. 6606 - 6609 (2011/07/30)
Functionalized carbene ligands: Increasing the steric bulk of R1 on 1 from H to tBu results in lengthening of the M-N bond (by up to 9 %), lowered activation energy for chelate opening (cf. 2) by 17 kcal mol -1, and improved binding
Efficient intramolecular hydroamination of unactivated alkenes catalysed by butyllithium
Ates, Ali,Quinet, Coralie
, p. 1623 - 1626 (2007/10/03)
In this communication, we wish to report some preliminary results demonstrating, for the first time, that intramolecular hydroamination of unactivated alkenes can be performed efficiently using small quantities of nBuLi as the pre-catalyst. Wiley-VCH Verl
