871586-98-0Relevant academic research and scientific papers
Valence isomerization of 2-phosphabicyclo-[1.1.0]butanes
Slootweg, J. Chris,Krill, Steffen,De Kanter, Frans J. J.,Schakel, Marius,Ehlers, Andreas W.,Lutz, Martin,Spek, Anthony L.,Lammertsma, Koop
, p. 6579 - 6582 (2007/10/03)
(Figure Presented) Remarkably stable 2-phosphabicyclo-[1.1.0]butanes (see picture; O red, P violet, W turquoise) were synthesized from the complexed phosphinidene Ph-P=W(CO)5 and cyclopropenes. These compounds undergo valence isomerization to f
