871795-58-3Relevant academic research and scientific papers
Silver(I)-catalyzed novel cascade cyclization reactions: Incorporation of allenes into the isochromenes
Patil, Nitin T.,Pahadi, Nirmal K.,Yamamoto, Yoshinori
, p. 10096 - 10098 (2007/10/03)
The silver(I)-catalyzed reaction of alkynones with alcohols represents a general tool for the synthesis of 1-allenyl isochromenes. The reaction most probably proceeds via the formation of benzopyrylium cation, which subsequently undergoes nucleophilic attack of an alcohol to give the annulation products.
