871810-47-8

Basic information

• Product Name: palladium(II)(Ph₂PC₆H₄₀₂-(CH₂NMe₂))(SC₆F₅)2
• CAS NO: 871810-47-8
• Molecular Weight: 824.054
• Mol File: 871810-47-8.mol

Chemical Properties

• CAS DataBase Reference: palladium(II)(Ph₂PC₆H₄₀₂-(CH₂NMe₂))(SC₆F₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: palladium(II)(Ph₂PC₆H₄₀₂-(CH₂NMe₂))(SC₆F₅)2(871810-47-8)
• EPA Substance Registry System: palladium(II)(Ph₂PC₆H₄₀₂-(CH₂NMe₂))(SC₆F₅)2(871810-47-8)

Safety Data

• Hazardous Substances Data: 871810-47-8(Hazardous Substances Data)

Upstream product

• 53881-33-7 [2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane 

Relevant articles and documents

Pd catalyzed Heck reaction with the catalytic system [Pd(Ph 2PC6H4-2-(CH2NMe2)) (SRF)2]: Examination of the electronic effects of fluorinated thiolates

A series of palladium thiolate complexes of the [Pd(Ph2PC 6H4-2-(CH2NMe2))(SR F)2] type have been synthesized in good yields by metathetical reactions of [Pd(Ph2PC6H4-2- (CH2NMe2))Cl2] (1) with [Pb(SR F)2], (SRF = S-C6F5, S-C6F4-4-H, S-C6H4-2-CF3, S-C6H4-4-F, S-C6H4-2-F) and their crystal structures determined. Heck coupling reactions were carried out using [Pd(Ph2PC6H4-2-(CH2NMe 2))(SRF)2], SRF = S-C 6F5 (2), S-C6F4-4-H (3), S-C 6H4-2-CF3 (4), S-C6H4-4-F (5), S-C6H4-2-F (6) complexes as catalysts in order to examine the effect of the thiolates in the reaction of bromobenzene and styrene. The results obtained indicate that the less electron-withdrawing substituents on the thiolate moiety may favor higher yields in the Pd catalyzed Heck reaction using [Pd(Ph2PC6H4-2-(CH2NMe 2))(SRF)2] as catalysts.