87183-81-1

Basic information

• Product Name: (η5-pentaphenylcyclopentadienyl)(η3-methylallyl)palladium(II)
• Synonyms: (η5-pentaphenylcyclopentadienyl)(η3-methylallyl)palladium(II)
• CAS NO: 87183-81-1
• Molecular Weight: 607.103
• Mol File: 87183-81-1.mol

Chemical Properties

• CAS DataBase Reference: (η5-pentaphenylcyclopentadienyl)(η3-methylallyl)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-pentaphenylcyclopentadienyl)(η3-methylallyl)palladium(II)(87183-81-1)
• EPA Substance Registry System: (η5-pentaphenylcyclopentadienyl)(η3-methylallyl)palladium(II)(87183-81-1)

Safety Data

• Hazardous Substances Data: 87183-81-1(Hazardous Substances Data)

Upstream product

• 5724-11-8 5-chloro-1,2,3,4,5-pentaphenylcyclopentadiene 

Relevant articles and documents

Direct synthesis of pentaphenylcyclopentadienyl complexes of palladium

A series of pentaphenylcyclopentadienyl complexes of palladium(II) of the type (η5-C5Ph5)(η3-all)Pd (all = allyl, 2-chloroallyl, 2-methylallyl, 1-methylallyl, 1,1-dimethylallyl, 1-carbomethoxyallyl) have been prepared in high yield from the reaction of NaC5Ph5 with [(η3-all)PdCl]2 in THF. Reaction of (η5-C5Ph5)(η3-all)Pd with phosphorus donor ligands results in the formation of zerovalent palladium complexes and coupled organic products. Reaction of (η5-C5Ph5)(η 3-2-chloroallyl)Pd with PR3 ligands gives a series of complexes (η5-C5Ph5)PdCl(PR3) that are not synthetically accessible from the reaction of NaC5Ph5 with [PdCl2(PR3)]2. Pyrolysis of (η5-C5Ph5)(2-chloroallyl)Pd gives allene and the chloro-bridged dimer [(η5-C5Ph5)PdCl]2. Reduction of this dimer by activated zinc dust in the presence of RC≡CR′ or CO gives the palladium(I) dimers (η5-C5Ph5) 2(μ-RC≡CR′)Pd2 and (η5-C5Ph5)2(μ-CO) 2Pd2, respectively.