871948-11-7

Upstream product

• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 7757-38-2 2,3,5,6-di-O-isopropylidene-D-mannofuranose 
• 31238-57-0 diphenyl(phenylthiomethyl)phosphine oxide 
• 13884-92-9 phenylthiomethyl triphenylphosphonium chloride 
• 34884-33-8 (phenylthio)-methylenetriphenylphosphorane 

Downstream Products

• 871948-18-4 phenyl 2-deoxy-2-iodo-3,4:6,7-di-O-isopropylidene-1-thio-D-glycero-α-D-taloheptopyranoside 
• 473829-91-3 (3aR,4R,7aR)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran 

Relevant academic research and scientific papers

Stereoselective synthesis of 2-deoxy-2-iodo-glycosides from furanoses. A new route to 2-deoxy-glycosides and 2-deoxy-oligosaccharides of ribo and xylo configuration

A general procedure for the stereoselective synthesis of 2-deoxy-2-iodo-hexo- and -hepto-pyranosyl glycosides from furanoses is reported. The proposed methodology provides a new route for accessing 2-deoxy-oligosaccharides. The procedure involves three re

Wittig approach to carbohydrate-derived vinyl sulfides, new substrates for regiocontrolled ring-closure reactions

Reaction of methyl- and phenylthiomethylidene phosphoranes 1 and 2 with a variety of reducing sugars has been explored. Furano-type carbohydrates afforded with good yields the corresponding open-chain vinyl sulfides, whereas pyrano derivatives produced elimination compounds together with the expected vinyl sulfides, depending on the nature of the protective groups.