872053-63-9Relevant academic research and scientific papers
α-Bromoacrylic Acids as C1 Insertion Units for Palladium-Catalyzed Decarboxylative Synthesis of Diverse Dibenzofulvenes
Zhang, Minghao,Deng, Wenbo,Sun, Mingjie,Zhou, Liwei,Deng, Guobo,Liang, Yun,Yang, Yuan
, p. 5744 - 5749 (2021/08/18)
Herein α-bromoacrylic acids have been employed as C1 insertion units to achieve the palladium-catalyzed [4 + 1] annulation of 2-iodobiphenyls, which provides an efficient platform for the construction of diverse dibenzofulvenes. This protocol enables the formation of double C(aryl)-C(vinyl) bonds via a C(vinyl)-Br bond cleavage and decarboxylation. It is particularly noteworthy that the method features a broad substrate scope, and various interesting frameworks, such as bridged ring, fused (hetero)aromatic ring, and divinylbenzene, can be successfully incorporated into the products.
Palladium catalyzed atom-economic synthesis of functionalized 9-(diarylmethylene)-9H-fluorenes using triarylbismuths in one-pot bis-coupling process
Rao, Maddali L.N.,Dasgupta, Priyabrata
supporting information; experimental part, p. 162 - 165 (2012/01/30)
An efficient palladium catalyzed atom-economic synthesis of functionalized 9-(diarylmethylene)-9H-fluorenes has been accomplished in one-pot bis-coupling process using triarylbismuths as organometallic reagents. These bis-couplings in 1 hour short reactio
Dications of fluorenylidenes. The relationship between redox potentials and antiaromaticity for meta- and para-substituted diphenylmethylidenefluorenes
Mills, Nancy S.,Tirla, Cornelia,Benish, Michele A.,Rakowitz, Amber J.,Bebell, Lisa M.,Hurd, Caroline M. M.,Bria, Anna L. M.
, p. 10709 - 10716 (2007/10/03)
Electrochemical oxidation of meta-substituted diphenylmethylidenefluorenes (3a-g) results in the formation of fluorenylidene dications that are shown to be antiaromatic through calculation of the nucleus independent chemical shift (NICS) for the 5- and 6-
Substituent Effects on Electron Spin Distribution and Conformation of Radical Ions obtained from 9-Diphenylmethylenefluorenes
Franco, M. Luisa T. M. B.,Herold, Bernardo J.,Evans, Jeffrey C.,Rowlands, Christopher C.
, p. 443 - 450 (2007/10/02)
Nine new substituted 9-diphenylmethylenefluorenes were synthetized.The reductions of the unsubstituted hydrocarbon and eleven substituted derivatives were studied by cyclic voltammetry in dimethylformamide solution.E.s.r. and ENDOR spectra of the radical anions obtained by reduction with alkali metal in tetrahydrofuran were recorded.The electron spin distribution as obtained from experiment was compared with the results of Hueckel-McLachlan calculations.The conformations of the radical anions were determined from the spectra.The ratio of electron spin densities in the fluorene part of the alkene and in the diphenylmethylene group obeys a linear Hammett correlation.A similar study was performed for the radical cations of six of the twelve alkenes.
