87207-03-2Relevant academic research and scientific papers
Mechanoactivation of solid-phase iodochlorination of olefins with potassium dichloroiodate(I)
Sereda,Zyk,Bulanov,Skadchenko,Volkov,Zefirov
, p. 2239 - 2240 (2007/10/03)
Mechanoactivation of iodochlorination of olefins with a new reagent, potassium dichloroiodate(I), was studied.
Reactions of Iodine(I) Azide with αβ-Unsaturated Carbonyl Compounds
Cambie, Richard C.,Jurlina, Jeffrey L.,Rutledge, Peter S.,Swedlund, Bernard E.,Woodgate, Paul D.
, p. 327 - 334 (2007/10/02)
The addition of iodine(I) azide to some αβ-unsaturated esters and ketones has been examined.Addition to the esters under nitrogen gives products consistent with a radical pathway.Preliminary kinetic results indicate that addition of iodine(I) azide to αβ-unsaturated ketones in the presence of air involves a slow electrophilic attack.Reaction with methyl trans-cinnamate under these conditions does not go to completion.
