872164-99-3

Basic information

• Product Name: Glycine, N-(2-bromo-1-oxopropyl)-N-(phenylmethyl)-, ethyl ester
• CAS NO: 872164-99-3
• Molecular Formula: C14H18BrNO3
• Molecular Weight: 328.206
• Mol File: 872164-99-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Glycine, N-(2-bromo-1-oxopropyl)-N-(phenylmethyl)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Glycine, N-(2-bromo-1-oxopropyl)-N-(phenylmethyl)-, ethyl ester(872164-99-3)
• EPA Substance Registry System: Glycine, N-(2-bromo-1-oxopropyl)-N-(phenylmethyl)-, ethyl ester(872164-99-3)

Safety Data

• Hazardous Substances Data: 872164-99-3(Hazardous Substances Data)

Upstream product

• 6436-90-4 ethyl 2-(benzylamino)acetate 
• 563-76-8 α-bromopropionyl bromide 
• 100-46-9 benzylamine 

Relevant articles and documents

Electrogenerated cyanomethyl anion in organic synthesis: A simple diastereoselective synthesis of cis-3-alkyl-1-benzyl-4-ethoxycarbonyl-β- lactams

A ready diastereoselective synthesis of cis-3-alkyl-1-benzyl-4- ethoxycarbonyl-β-lactams has been developed by galvanostatic electrolysis of MeCN-Et4NPF6 solutions and subsequent addition of a N-(ethoxycarbonyl)methyl-N-benzyl-2-bromoalkylcarboxamide. The yields in β-lactams are very high and the cis isomers have been obtained in a large excess, the cis/trans ratios varying from 87/13 to 93/07.