87224-27-9Relevant articles and documents
Halogen displacement chemistry with silver and alkali metal salts: Preparation of SF5-esters, alcohols, aliphatic olefins, acids and an iodide
Winter,Gard
, p. 1188 - 1194 (2006)
It has been found that treatment of SF5-alkyl halides, especially SF5(CH2)2Br, with silver salts such as CH3C(O)OAg, p-CH3C6H4SO3Ag, CF3SO3
Synthesis of N-(2-SF5-ethyl)amines and impact of the SF5 substituent on their basicity and lipophilicity
Gilbert, Audrey,Langowski, Pauline,Paquin, Jean-Fran?ois
, (2021/09/13)
The synthesis of N-(2-SF5-ethyl)amines is reported via the SN2 reaction between various amines and 2-(pentafluoro-λ6-sulfanyl)ethyl trifluoromethanesulfonate as the SF5-containing electrophile. A total of 14 exa
One-pot syntheses of 1,2,3-triazoles containing a pentafluorosulfanylalkyl group via click chemistry
Huang, Yangen,Gard, Gary L.,Shreeve, Jean'Ne M.
scheme or table, p. 6951 - 6954 (2011/03/18)
1,4-Disubstituted 1,2,3-triazoles containing a pentafluorosulfanylalkyl group were synthesized in good to excellent yields (57-91%) by the click cycloadditions of in situ generated SF5-alkyl azides with aromatic and aliphatic alkynes. Nucleophi
Sulfuranonium Ions, R-SF4+, Preparation, Evidence, and Stability
Wessel, Juergen,Kleemann, Gert,Seppelt, Konrad
, p. 2399 - 2407 (2007/10/02)
Sulfuranonium Ions of the type R-SF4+ are generated from R-SF5 by fluoride ion abstraction with SbF5.In spite of large variation of R (CH3, CH=CH2, CCH a. o.) none of the ions is stable at room temperature.The ions were identified by NMR met
