872290-35-2Relevant academic research and scientific papers
Stereochemical and regiochemical studies on the alkylation of pentane-2,4-dione through its Co(II) complex
Vallribera,Serra,Marquet,Moreno-Manas
, p. 6451 - 6462 (1993)
Stereochemical and regiochemical results on the alkylation of pentane-2,4-dione with benzyl and allyl halides, through its Co(II) complex in concentrated chloroform solution are interpreted in terms of the mechanistic scheme proposed in the preceding pape
The thermal desulfination of allylic sulfonyl halides
King, Malcolm D.,Sue, Rodney E.,White, Rodney H.,Young, David J.
, p. 4493 - 4496 (2007/10/03)
Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with γ-syn bromine migration.
Dibenzofurancarboxamides and their pharmaceutical compositions and methods
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, (2008/06/13)
This invention is directed to certain dibenzofurancarboxamides and their use as 5HT3 antagonists having unique CNS, anti-emetic and gastric prokinetic activity void of any significant D2 receptor binding properties. This invention also describes novel processes necessary for their preparation.
