872333-46-5Relevant academic research and scientific papers
Synthesis of the β anomer of the spacer-equipped tetrasaccharide side chain of the major glycoprotein of the Bacillus anthracis exosporium
Adamo, Roberto,Saksena, Rina,Kovac, Pavol
, p. 2579 - 2582 (2005)
The β glycoside of the tetrasaccharide sequence β-Ant-(1→3)- α-l-Rhap-(1→3)-α-l-Rhap-(1→2)-l-Rhap, whose aglycon allows conjugation to proteins, was synthesized for the first time. A stepwise synthetic approach was applied with thioglycosides as glycosyl
Immunogens related to the synthetic tetrasaccharide side chain of the Bacillus anthracis exosporium
Saksena, Rina,Adamo, Roberto,Kovac, Pavol
, p. 4283 - 4310 (2008/03/14)
The known methyl 2-O-acetyl-3,4-di-O-benzyl-1-thio-α-l-rhamnopyranoside (3) was converted to the corresponding 5-methoxycarbonylpentyl glycoside 4 which was deacetylated. The product 5 was used as the initial glycosyl acceptor to construct two trirhamnosi
Synthesis of the tetrasaccharide side chain of the major glycoprotein of the Bacillus anthracis exosporium
Saksena, Rina,Adamo, Roberto,Kovac, Pavol
, p. 615 - 617 (2007/10/03)
An α-glycoside of the tetrasaccharide sequence β-Ant-(1 → 3)-α-L-Rhap-(1 → 3)-α-L-Rhap-(1 → 2)-α-L-Rhap whose aglycon allows conjugation to suitable carriers was synthesized. The NMR characteristics of the compound are virtually identical with those of th
