872359-59-6

Basic information

• Product Name: (R)-10-Trimethylsilanyl-9-(3-trimethylsilanyl-prop-2-ynyl)-9-bora-bicyclo[3.3.2]decane
• Synonyms: (R)-10-Trimethylsilanyl-9-(3-trimethylsilanyl-prop-2-ynyl)-9-bora-bicyclo[3.3.2]decane
• CAS NO: 872359-59-6
• Molecular Weight: 318.458
• Mol File: 872359-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-10-Trimethylsilanyl-9-(3-trimethylsilanyl-prop-2-ynyl)-9-bora-bicyclo[3.3.2]decane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-10-Trimethylsilanyl-9-(3-trimethylsilanyl-prop-2-ynyl)-9-bora-bicyclo[3.3.2]decane(872359-59-6)
• EPA Substance Registry System: (R)-10-Trimethylsilanyl-9-(3-trimethylsilanyl-prop-2-ynyl)-9-bora-bicyclo[3.3.2]decane(872359-59-6)

Safety Data

• Hazardous Substances Data: 872359-59-6(Hazardous Substances Data)

Upstream product

• 848618-13-3 9-(1S,2S-pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane 
• 78012-45-0 [3-(trimethylsilyl)prop-2-yn-1-yl]magnesium bromide 

Downstream Products

• 856676-11-4 (1R,2R)-N-methyl-1-phenyl-1-(((1S,5S,10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]decan-9-yl)oxy)propan-2-amine 
• 848618-13-3 9-(1S,2S-pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane 
• 872359-75-6 (R)-9-((S)-1-Phenyl-2-trimethylsilanyl-buta-2,3-dienyloxy)-10-trimethylsilanyl-9-bora-bicyclo[3.3.2]decane 

Relevant articles and documents

Nonracemic α-allenyl carbinols from asymmetric propargylation with the 10-trimethylsilyl-9-borabicyclo[3.3.2]decanes

(Chemical Equation Presented) The asymmetric propargylboration of aldehydes at -78°C in 98% ee). The reagents 1 are easily prepared in both enantiomeric forms with a simple Grignard procedure and air-stable borinate complexes 2. The ozonolysis of 6 proceeds smoothly through an acylsilane intermediate to give a TMS ester, which is hydrolyzed to the α-hydroxy acid quantitatively with water.