87238-58-2Relevant academic research and scientific papers
SYNTHESIS OF 9-HEXADECEN-15-OLIDES; HYPOTHETICAL INTERMEDIATES IN THE BIOSYNTHESIS OF BREFELDIN A
Ohta, Tomihisa,Sunagawa, Masayuki,Nishimaki, Kazuko,Nozoe, Shigeo
, p. 1567 - 1576 (2007/10/02)
Four types of lactones 1-4 which might be biosynthetic intermediates of brefeldin A have been synthesized.In the course of their synthesis, it was found that coupling of a hydroxy phosphonium salt and a carbomethoxy-aldehyde gave a macrocyclic lactone in
