872467-62-4

Basic information

• Product Name: Mn(II)(pyridine)2(diphenyldithiocarbamato)2
• CAS NO: 872467-62-4
• Molecular Weight: 701.863
• Mol File: 872467-62-4.mol

Chemical Properties

• CAS DataBase Reference: Mn(II)(pyridine)2(diphenyldithiocarbamato)2(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(II)(pyridine)2(diphenyldithiocarbamato)2(872467-62-4)
• EPA Substance Registry System: Mn(II)(pyridine)2(diphenyldithiocarbamato)2(872467-62-4)

Safety Data

• Hazardous Substances Data: 872467-62-4(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 2801-05-0 sodium N,N-diphenyldithiocarbamate 
• 14872-18-5 bis(pyridine)manganese(II) chloride 

Relevant articles and documents

Synthesis, characterization and thermal studies of bipyridine metal complexes containing different substituted dithiocarbamates

Complexes of the type [Mpy2(dedtc)2], and [Mpy 2(dpdtc)2], where M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), py = pyridine, dedtc = diethyldithiocarbamate and dpdtc = diphenyldithiocarbamate, have been synthesized and characterized by elemental analyses, magnetic susceptibility, TGA/DSC and IR in the solid-state, and electronic spectroscopy and conductivity measurement studies in solution. The dithiocarbamato moiety has been found to be symmetrically bonded to the metal. The complexes are proposed to have a distorted-octahedral structure. The ligand field parameters 10 Dq, B and β have also been evaluated. The value of β indicates a considerable orbital overlap in the complexes. A two-stage decomposition pattern leading to the formation of respective metal sulfide as the end-product has been observed in all the complexes. Their molar conductance indicated them to be non-electrolyte in nitrobenzene. Copyright