872474-08-3Relevant academic research and scientific papers
Controllable molecular configuration for significant improvement of blue OLEDs based on novel twisted anthracene derivatives
Wang, Juan,Lou, Xia,Liu, Yaqing,Zhao, Guizhe,Islam, Amjad,Wang, Suidong,Ge, Ziyi
, p. 137 - 144 (2015)
Two novel twisted anthracene derivatives, 2-(4-(10-(phenanthren-9-yl)anthracen-9-yl)phenyl)-1-phenyl-1H-phenanthro[9,10-d]-imidazole (p-PABPI) and 2-(3-(10-(phenan-thren-9-yl)anthracen-9-yl)phenyl)-1-phenyl-1H-phenanthro-[9,10-d]imidazole (m-PABPI), have been synthesized. Their photophysical and photochemical properties are also investigated systemically. The non-doped fluorescent organic light-emitting diodes are fabricated by using anthracene derivatives as the emitters. The maximum current efficiencies are achieved to be 3.98 and 1.32 cd A-1 and the maximum power efficiencies are 2.80 and 1.14 lm W-1, respectively. The external quantum efficiency maximum (EQEmax) is 3.61% and 1.33% for p-PABPI and m-PABPI. Intriguingly, the efficiencies of p-PABPI are almost three times larger than that of m-PABPI with only the different molecular configuration. The results revealed a new rule of molecular design based on anthracene derivatives for obtaining high performance blue emission materials.
ORGANIC ELECTROLUMINESCENT ELEMENT
-
, (2008/06/13)
The novel compound of the present invention has the diphenylanthracene structure at the center and a specific structure substituted with an aryl group at end portions. The organic electroluminescence device of the present invention comprises a plurality of layers of thin films of organic compounds which comprise a light emitting layer or a plurality of layers comprising a light emitting layer and are disposed between a pair of electrodes and at least one of the layers of thin films of organic compounds comprises the above novel compound. The novel compound exhibits excellent efficiency of light emission and heat resistance, has a long life and emits bluish light having excellent purity of color and the organic electroluminescence device comprises the novel compound and exhibits the same advantageous properties.
