872513-62-7

Basic information

• Product Name: 2,4-bis(1,1-dimethylethyl)-6-[[[2-[(4-methoxyphenyl)thio]phenyl]imino]methyl]phenol
• Synonyms: 2,4-bis(1,1-dimethylethyl)-6-[[[2-[(4-methoxyphenyl)thio]phenyl]imino]methyl]phenol
• CAS NO: 872513-62-7
• Molecular Weight: 447.642
• Mol File: 872513-62-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4-bis(1,1-dimethylethyl)-6-[[[2-[(4-methoxyphenyl)thio]phenyl]imino]methyl]phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-bis(1,1-dimethylethyl)-6-[[[2-[(4-methoxyphenyl)thio]phenyl]imino]methyl]phenol(872513-62-7)
• EPA Substance Registry System: 2,4-bis(1,1-dimethylethyl)-6-[[[2-[(4-methoxyphenyl)thio]phenyl]imino]methyl]phenol(872513-62-7)

Safety Data

• Hazardous Substances Data: 872513-62-7(Hazardous Substances Data)

Upstream product

• 3169-69-5 4-methoxyphenyl-2-nitrophenylsulfide 
• 1493-27-2 ortho-nitrofluorobenzene 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 3169-87-7 2-[(4-methoxyphenyl)thio]benzenamine 

Downstream Products

• 872513-69-4 [N-(3,5-di-tert-butylsalicylidene)-2-(4-methoxylphenylsulfanyl)anilinato]Ti(IV)Cl₃ 

Relevant articles and documents

Iridium and phosphine promoted C-F bond activation: The C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers

Carbon-fluorine bond is the strongest known single bond to carbon and proved very difficult to cleave. An iridium and phosphine promoted C-F bond activation was developed, for the first time achieving the C-S cross-coupling reaction of disulfides with aryl fluorides using iridium complex. The corresponding monoarylthiolation products were obtained at moderate to good yields. Thus, it represents a new method for the synthesis of aryl sulfides through C-F bond activation.