Welcome to LookChem.com Sign In|Join Free

CAS

  • or

872515-42-9

((2,6-(CHMe2)2C6H3NC(Me)CH(Me)CNC6H3(CHMe2)2-2,6)Ir(1,5-cyclooctadiene)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

872515-42-9 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 872515-42-9 Structure

  • Basic information

    1. Product Name: ((2,6-(CHMe2)2C6H3NC(Me)CH(Me)CNC6H3(CHMe2)2-2,6)Ir(1,5-cyclooctadiene)]
    2. Synonyms:
    3. CAS NO:872515-42-9
    4. Molecular Formula:
    5. Molecular Weight: 718.061
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 872515-42-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: ((2,6-(CHMe2)2C6H3NC(Me)CH(Me)CNC6H3(CHMe2)2-2,6)Ir(1,5-cyclooctadiene)](CAS DataBase Reference)
    10. NIST Chemistry Reference: ((2,6-(CHMe2)2C6H3NC(Me)CH(Me)CNC6H3(CHMe2)2-2,6)Ir(1,5-cyclooctadiene)](872515-42-9)
    11. EPA Substance Registry System: ((2,6-(CHMe2)2C6H3NC(Me)CH(Me)CNC6H3(CHMe2)2-2,6)Ir(1,5-cyclooctadiene)](872515-42-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 872515-42-9(Hazardous Substances Data)

872515-42-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 872515-42-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,7,2,5,1 and 5 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 872515-42:
(8*8)+(7*7)+(6*2)+(5*5)+(4*1)+(3*5)+(2*4)+(1*2)=179
179 % 10 = 9
So 872515-42-9 is a valid CAS Registry Number.

872515-42-9Relevant articles and documents

Ancillary ligand effects on C-H bond activation reactions promoted by β-diiminate iridium complexes

Bernskoetter, Wesley H.,Lobkovsky, Emil,Chirik, Paul J.

, p. 6250 - 6259 (2008/10/09)

A series of β-diiminate iridium(I) olefin, diolefin, and hydride complexes have been synthesized and evaluated in carbon-hydrogen bond activation reactions. Treatment of [Ir-(COE)2Cl]2 (COE = cyclooctene) with the lithio β-diiminate anions [Li(OEt2)] [BDI] (BDI = ArNC(Me)CH(Me)CNAr; Ar = 2,6-Me2C6H3, 2,6-Et2C6H3, 2,6-iPr 2C6H3) under an N2 atmosphere furnished the corresponding iridium(I) cycloctene dinitrogen complexes. Using a similar procedure, the analogous β-diiminate iridium(I) cyclooctadiene compounds have also been prepared and characterized. Addition of the sterically demanding β-diiminate anion (2,6-Me2C6H 3)NC(CMe3)CH(CMe3)CN(2,6-Me2C 6H3) to [Ir(COD)Cl]2 (COD = 1,5-cyclooctadiene) yielded an unusual η5-arene complex that is stabilized by a significant contribution from an iminocyclohexadienyl resonance form. The relative electronic influence of each β-diiminate ligand has been evaluated by preparation of the corresponding iridium dicarbonyl complexes and reveals little electronic perturbation among alkyl substituents on the aryl rings. With respect to C-H bond activation, warming the β-diiminate iridium(I) cyclooctene dinitrogen compounds to 50°C resulted in intramolecular dehydrogenation chemistry, the outcome of which is dependent on the β-diiminate aryl substituents. For the 2,6-dimethyl-substituted complex, transfer dehydrogenation of the cyclooctene ligand is observed, while for the larger diethyl- and diisopropyl-substituted variants, dehydrogenation of the aryl substituents occurs.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 872515-42-9