87252-06-0Relevant articles and documents
Reaction of Pyrazine-2,3-dicarbonitrile and 1,3-Dimethyllumazine with Alkyl Radicals
Tada, Masaru,Ito, Takayori,Ohshima, Kaoru
, p. 1893 - 1896 (2007/10/02)
Pyrazine-2,3-dicarbonitrile (1) reacts with alkyl radicals to give mono- 3 and di-alkylated pyrazine-2,3-dicarbonitriles 4.Similarly 1,3-dimethyllumazine (2) reacts with alkyl radicals to give 7-alkyl-1,3-dimethyllumazines 8 as a major product.The reactivity of alkyl radicals decreases in the order tertiary, secondary, and primary, and 1 is more reactive than 2 in those radical substitution reactions.
Structure-activity Relationship of Herbicidal 2,3-Dicyano-5-Substituted Pyrazines
Nakamura, Akira,Ataka, Toshiei,Segawa, Hirozo,Takeuchi, Yasutomo,Takematsu, Tetsuo
, p. 1555 - 1560 (2007/10/02)
Sixty six 2,3-dicyano-5-substituted pyrazines were synthesized and their herbicidal activities against barnyard grass were measured in pot tests to clarify the relationship between chemical structure and activity.The activity of 59 derivatives was related parabolically to the hydrophobic substituent parameter at the 5-position of the pyrazine ring.