872525-86-5

Upstream product

• 872525-85-4 Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5aR,6S,9aS,9bR)-5a-formyl-2,2-dimethyl-5,8-dioxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester 
• 872525-98-9 (3aR,7aS)-2,2-Dimethyl-6-oxo-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carbaldehyde 
• 872525-77-4 2-(5-formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide 
• 872525-78-5 2-(2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide 
• 872525-80-9 (3aS,7aR)-6-Hydroxymethyl-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-ol 
• 872525-76-3 2-(5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide 
• 872525-79-6 4-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-2-methylene-butane-1,3-diol 
• 146919-01-9 3,4-O-isopropylidene-2-deoxy-D-ribono-1,5-lactone 
• 135951-18-7 ((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-acetaldehyde 
• 86795-44-0 3,4-O-isopropylidene-2-deoxy-D-ribose 
• 22900-10-3 2-deoxy-D-ribose 
• 872525-84-3 6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester 

Downstream Products

• 872525-93-4 C₅₀H₇₄O₉Si₂ 
• 872525-94-5 C₅₀H₆₄O₉SeSi 
• 872525-89-8 acetic acid 17-(tert-butyl-diphenyl-silanyloxymethyl)-4,14-dihydroxy-13-methyl-1,7-dioxo-10-(2-trimethylsilanyl-ethoxymethoxymethyl)-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-11-yl ester 
• 872525-92-3 C₄₄H₆₀O₉Si 
• 872525-95-6 C₄₄H₅₈O₉Si 
• 872525-91-2 C₄₄H₆₀O₉Si 
• 872525-90-1 Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5S,5aR,6S,9aS,9bR)-5-hydroxy-5a-hydroxymethyl-2,2-dimethyl-8-oxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester 
• 872525-87-6 Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-[(3aS,5aR,6S,9aS,9bR)-2,2-dimethyl-5,8-dioxo-5a-(2-trimethylsilanyl-ethoxymethoxymethyl)-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl]-ethyl ester 

Relevant academic research and scientific papers

Studies towards the total synthesis of ouabagenin

An anionic cyclization strategy developed in our laboratory was used to produce a versatile and convergent synthesis of an advanced tetracyclic intermediate for the construction of ouabagenin and closely related analogs.