87255-14-9Relevant academic research and scientific papers
A nine carbon homologating system for skip-conjugated polyenes
Mustafa, Hussein H.,Baird, Mark S.,Al Dulayymi, Juma'A R.,Tverezovskiy, Viacheslav V.
, p. 34 - 42 (2014/07/08)
Ozonolysis of Z,Z,Z-cylonona-1,4,7-triene leads to a 1,9-difunctionalised Z,Z-3,6-nonadiene which is readily converted into a range of polyunsaturated pheromones and fatty acids.
Facile and efficient syntheses of (3Z,6Z,9Z)-3,6,9-nonadecatriene and homologues: Pheromone and attractant components of lepidoptera
Wang, Shifa,Zhang, Aijun
, p. 6929 - 6932 (2008/09/17)
Facile and efficient chemical syntheses of (3Z,6Z,9Z)-3,6,9-nonadecatriene and homologues from commercially available α-linolenic acid [(9Z,12Z,15Z)-9,12,15-octadecatrienoic acid] are reported. These straight-chain homoconjugated trienes are common sex pheromone and attractant components for many lepidopterous insect pests. The metal-catalyzed cross-coupling reactions between (9Z,12Z,15Z)-9,12,15-octadecatrienyl triflate and the appropriate Grignard reagents proceed very rapidly under notable mild conditions using Li2CuCl4 as catalyst in diethyl ether, and the resulting (3Z,6Z,9Z)-3,6,9-trienes with retention of geometrical configuration were in >92% isolated yield.
Pheromones, 57.- Synthesis of Lepidoptera Polyene Pheromones and of Structural Analogs.- Acetylenic Synthesis, Wittig Olefination, and Kolbe Electrolysis
Bestmann, Hans Juergen,Roth, Kurt,Michaelis, Karl,Vostrowsky, Otto,Schaefer, Hans J.,Michaelis, Ralf
, p. 417 - 422 (2007/10/02)
By a combination of acetylenic syntheses with Wittig olefination as well as by mixed Kolbe electrolysis alkadienes, alkatrienes, and alkatetraenes (sex attractants of Lepidoptera and structural analogs)were synthesized.
