87258-16-0

Basic information

• Product Name: tetraformyltetrathiafulvalene-bis(diethyl acetal)
• Synonyms: tetraformyltetrathiafulvalene-bis(diethyl acetal)
• CAS NO: 87258-16-0
• Molecular Weight: 464.649
• Mol File: 87258-16-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetraformyltetrathiafulvalene-bis(diethyl acetal)(CAS DataBase Reference)
• NIST Chemistry Reference: tetraformyltetrathiafulvalene-bis(diethyl acetal)(87258-16-0)
• EPA Substance Registry System: tetraformyltetrathiafulvalene-bis(diethyl acetal)(87258-16-0)

Safety Data

• Hazardous Substances Data: 87258-16-0(Hazardous Substances Data)

Upstream product

• 930-35-8 1,3-dithiol-2-thione 
• 87258-15-9 4-formyl-5-(diethoxymethyl)-1,3-dithiole-2-thione 

Downstream Products

• 132091-82-8 C₅₂H₇₀N₈O₈P₂S₁₀ 
• 142409-24-3 4,5,4',5'-Tetrakis-((E)-styryl)-[2,2']bi[[1,3]dithiolylidene] 

Relevant articles and documents

Highly extended, planar and sulfur-rich tetrathiafulvalene derivatives: Towards an increased dimensionality of organic metals

Highly extended π-donors 1-3 have been obtained through twofold or fourfold Wittig olefinations of polyformyl tetrathiafulvalenes with P-ylids bearing the 1,3-dithiol-2-ylidene moiety. Their powerful π-donor properties as well as their ability to generate cation-radical salts of mixed valency have been evaluated by both classical and thin layer cyclic voltammetry. Such extended π-donors prove to be planar in the neutral state, with very short intramolecular S...S distances, as demonstrated by the X-ray diffraction study of the model compound 16b. Such extended sulfur-rich tetrathiafulvalene derivatives are prone to generate highly dimensional materials as demonstrated in the case of the 3a.ClO4 cation-radical salt which presents a unique type of two-dimensional network in the solid-state. Elsevier,.