872593-76-5

Upstream product

• 219518-19-1 4-methylphenyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 755002-38-1 p-tolyl 4,6-O-benzylidene-3-O-p-toluenesulfonyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 1404060-66-7 methyl 4-O-(2,3-anhydro-4,6-O-benzylidene-α-D-allopyranosyl)-2,3-di-O-benzyl-6-deoxy-α-D-glucopyranoside 
• 1404060-67-8 methyl 4-O-(2,3-anhydro-4,6-di-O-benzylidene-β-D-allopyranosyl)-2,3-di-O-benzyl-6-deoxy-α-D-glucopyranoside 
• 1404060-85-0 methyl 4-S-(2,3-anhydro-4,6-di-O-acetyl-β-D-mannopyranosyl)-2,3-di-O-p-methoxybenzyl-6-deoxy-α-D-galactopyranoside 
• 1404060-84-9 methyl 4-S-(2,3-anhydro-4,6-di-O-acetyl-α-D-allopyranosyl)-2,3-di-O-p-methoxybenzyl-6-deoxy-α-D-galactopyranoside 
• 1404060-78-1 methyl 4-S-(2,3-anhydro-4,6-di-O-acetyl-α-D-allopyranosyl)-2,3-di-O-p-methoxybenzyl-6-deoxy-α-D-glucopyranoside 
• 1404060-77-0 p-tolyl 2,3-anhydro-4,6-di-O-acetyl-1-thio-β-D-allopyranoside 
• 881895-03-0 N-{(1R,2S,3R)-1-[(S)-1-Azido-2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,3,4-tris-benzyloxy-butyl}-acetamide 
• 881895-02-9 N-{(1R,2S,3R)-1-[(S)-1-Azido-2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,4-bis-benzyloxy-3-hydroxy-butyl}-acetamide 
• 881894-77-5 N-[(1R,2S,3R)-1-((S)-1-Azido-2-hydroxy-ethyl)-2,3,4-tris-benzyloxy-butyl]-acetamide 
• 881895-00-7 N-((2S,3S,4R,5S,6R)-3-Azido-5-benzyloxy-6-benzyloxymethyl-2-p-tolylsulfanyl-tetrahydro-pyran-4-yl)-acetamide 
• 881895-14-3 (2S,3S,4R,5S,6R)-3,4-Diazido-5-benzyloxy-6-benzyloxymethyl-2-p-tolylsulfanyl-tetrahydro-pyran 
• 881894-99-1 N-((2R,4aR,6S,7S,8R,8aS)-7-Azido-2-phenyl-6-p-tolylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-acetamide 
• 881895-01-8 N-[(1R,2S,3R)-1-((S)-1-Azido-2-hydroxy-ethyl)-2,4-bis-benzyloxy-3-hydroxy-butyl]-acetamide 
• 881894-97-9 (2R,4aR,6S,7S,8R,8aS)-7,8-Diazido-2-phenyl-6-p-tolylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine 

Relevant academic research and scientific papers

Base-promoted rearrangement of sugar epoxides to unsaturated sugars

(Chemical Equation Presented) A simple and efficient method for rearranging 2,3-anhydro carbohydrates to unsaturated sugars has been developed. The exceptionally mild reaction conditions and high stereoselectivity should make this an attractive method for the preparation of unsaturated carbohydrate derivatives.