872594-07-5

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 19165-12-9 Propyl-1-thio-β-D-glucopyranosid 
• 101-48-4 phenylacetaldehyde dimethyl acetal 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 41670-80-8 n-propyl 2,3,4,6-tetra-O-acetyl-1-thio-D-glucopyranoside 
• 83-87-4 D-glucose pentaacetate 

Downstream Products

• 872594-11-1 n-propyl 4,6-O-benzylidene-3-O-p-toluenesulfonyl-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Challenges in the Conversion of Manual Processes to Machine-Assisted Syntheses: Activation of Thioglycoside Donors with Aryl(trifluoroethyl)iodonium Triflimide

The steps needed to adapt a stable iodonium promoter for use in automated fluorous-assisted solution-phase oligosaccharide synthesis are described. Direct adaptation of the originally reported batch procedure resulted in the formation of an orthoester or

Base-promoted rearrangement of sugar epoxides to unsaturated sugars

(Chemical Equation Presented) A simple and efficient method for rearranging 2,3-anhydro carbohydrates to unsaturated sugars has been developed. The exceptionally mild reaction conditions and high stereoselectivity should make this an attractive method for the preparation of unsaturated carbohydrate derivatives.