872598-44-2

Usage

Uses

Used in Chemical Industry:
1-Me-AZADO is used as a catalyst for the aerobic oxidation of alcohols and sterically hindered alcohols, facilitating efficient and selective oxidation reactions in various chemical processes.

Upstream product

• 95-54-5 1,2-diamino-benzene 
• 100-46-9 benzylamine 
• 17933-29-8 7-methylenebicyclo[3.3.1]nonan-3-one 
• 5001-18-3 1,3-adamantandiol 
• 872598-38-4 7-methylene-bicyclo[3.3.1]nonan-3-one oxime 
• 872598-42-0 1-iodomethyl-2-azaadamantane 
• 872598-43-1 1-methyl-2-aza-tricyclo[3.3.1.1^3,7]decane 

Relevant academic research and scientific papers

Aerobic oxidative synthesis of benzimidazoles from amines catalyzed by 3-methyl-4-oxa-5-azahomoadamantane and iron(III) chloride

A simple and efficient catalytic system including 3-methyl-4-oxa-5- azahomoadamantane and FeCl3 for aerobic oxidative synthesis of benzimidazoles from primary amines and o-phenylenediamine is presented. This process uses O2 as economic and green oxidant and water as green solvent, tolerates a wide range of substrates, and can afford the target products in moderate to excellent yields.

2-Azaadamantane N-oxyl (AZADO) and 1-Me-AZADO: Highly efficient organocatalysts for oxidation of alcohols

Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl compounds in excellent yields. Copyright