87261-92-5Relevant academic research and scientific papers
Reaction of F Atoms with Methyl Nitrite. Infrared Spectroscopic Evidence for the Stabilization of FON in an Argon Matrix
Jacox, Marilyn E.
, p. 4940 - 4945 (1983)
When the products of the reaction between F atoms formed in a microwave discharge and methyl or methyl-d3 nitrite are frozen in a large excess of argon at 14 K, prominent absorptions of FNO appear in the infrared spectrum of the solid deposit, demonstrating that NO abstraction occurs.Two absorptions previously attributed to FON are also very prominent, supporting the identification of that isomer, but the assignment of the NO-stretching fundamental of FON was not confirmed.The appearance of infrared absorptions of isolated and hydrogen-bonded HF indicates that the more exothermic reaction channel involving H-atom abstraction also occurs.The absorptions of H2CO and NO, products of the decomposition of CH2ONO, are prominent, with indirect evidence that a small concentration of CH2ONO may have been stabilized.Factors influencing the relative contributions of the two observed F-atom reaction channels are considered.
Kinetics of the Reactions of CH2(X3B1) Radicals with NO and NO2
Seidler, V.,Temps, F.,Wagner, H. Gg.,Wolf, M.
, p. 1070 - 1073 (2007/10/02)
The kinetics of CH2 radicals in their triplet electronic ground state (X3B1) with NO and NO2 3B1) + NO -> products (1); CH2(X3B1) + NO2 -> products (2)> have been studied at room temperature in isothermal discharge flow systems.CH2 radicals were generated either by exciplex laser photolysis of CH2CO or via the reaction O + CH2CO -> CH2 + CO2.The CH2 concentration was monitored directly with a far-infrared laser magnetic resonance spectrometer.From the decay of under pseudo-first-order conditions the rate conatants of reactions 1 and 2 were obtained to be k1(296K) = (2.2 +/- 0.2) x 1E13 cm3/(mol s) and k2(296K) = (5.9 +/- 1.4) x 1E13 cm3/(mol s).
