87265-78-9

Upstream product

• 92737-70-7 (2R,3R)-3-Hydroxy-2,4-dimethyl-pent-4-enoic acid tert-butyl ester 
• 505-23-7 1,3 dithiane 
• 87265-74-5 2,3-syn-(Z)-3,4-epoxy-2-methylpentyl trityl ether 
• 87265-74-5 2,3-syn-(E)-3,4-epoxy-2-methylpentyl trityl ether 
• 87265-74-5 2,3-anti-(E)-3,4-epoxy-2-methylpentyl trityl ether 
• 87265-74-5 2,3-anti-(Z)-3,4-epoxy-2-methylpentyl trityl ether 
• 102745-52-8 (2S^*,3R^*)-2,4-dimethyl-4-pentene-1,3-diol 
• 92737-70-7 3-Hydroxy-2,4-dimethyl-pent-4-enoic acid tert-butyl ester 
• 87265-66-5 3,4-syn-3-t-butyldimethylsilyloxy-4-methyl-5-trityloxy-2-pentanone 
• 87265-69-8 2,3-syn-3,4-syn-3-t-butyldimethylsilyloxy-4-methyl-5-trityloxy-2-pentanol 
• 87265-65-4 3,4-syn-3-hydroxy-5-trityloxy-2-pentanone 
• 92737-72-9 (3R,4S)-2,4-Dimethyl-5-trityloxy-pent-1-en-3-ol 
• 87265-64-3 t-butyl 2,4-dimethyl-3-oxo-4-pentanoate 
• 84784-84-9 (S)-5-Hydroxy-2,4-dimethyl-pent-1-en-3-one 

Relevant academic research and scientific papers

STEREOSELECTIVE ACYCLIC KETONE REDUCTION. SYNTHESIS OF THE SYNTHONS HAVING THREE CONSECUTIVE CHIRAL CENTERS

Four possible diastereomers of a functionalized 1,3-dimethyl-2-hydroxy unit were synthesized based on the stereoselective reduction of various acyclic ketones (i.e. reduction of β-keto ester, β-hydroxy ketone, α-hydroxy ketone, and α-silyloxy ketone) and

STEREOSELECTIVE SYNTHESIS OF THE SYNTHONS HAVING THREE CONSECTIVE CHIRAL CENTERS

Four possible diastereomers having three consective chiral centers, R-CHMe-CHOH-CHMe-R', have been synthesized stereoselectively based on the stereoselective reduction of acyclic ketones.