872675-99-5

Upstream product

• 106-54-7 p-Chlorothiophenol 
• 27691-42-5 C₁₂H₉Cl₂NO₂S₂ 
• 3096-71-7 2,5-dimethyl-4-amino phenol 

Relevant academic research and scientific papers

Reaction of N-chloro-1,4-benzoquinone imines with thiols

N-Chloro-1,4-benzoquinone imines reacted with arenethiols to give different products, depending on the conditions and initial quinone imine structure. N-(Arylsulfanyl)-1,4-benzoquinone imines were obtained as a result of nucleophilic substitution of the chlorine atom, and 1,4-benzoquinone imines containing an aryl-sulfanyl substituent in the quinoid ring were formed according to the radical mechanism. The reactions of N-chloro-1,4-benzoquinone imines with heterocyclic thiols afforded only the corresponding chlorine substitution products.

Reactions of arylsulfinyl chlorides and N-(arylsulfonyl)arylsulfinimidoyl chlorides with p-aminophenols

In reactions of arylsulfinyl chlorides and N-(arylsulfonyl) arylsulfinimidoyl chlorides with p-aminophenols formed N-arylthio-1,4- benzoquinone imines, evidently through a stage of N-arylsulfinyl-4-aminophenols and N-(N-arylsulfonyl)arylsulfinylimidoyl-4-aminophenols that under the reaction conditions eliminate respectively H2O and ArSO2NH 2.