87273-67-4Relevant academic research and scientific papers
Evidence for the intermediacy of arylbenzylnitrenium ions in the thermal rearrangement of isoxazolidines derived from C,N-diarylnitrones and 2-morpholin-4-yl-acrylonitrile
Liard, Annie,Nguyen, Thi-Huu,Smir, Abdel Illah Djelloul,Vaultier, Michel,Derdour, Aicha,Mortier, Jacques
, p. 1000 - 1007 (2003)
In contrast to the diaryl, dialkyl, alkylaryl, and parent series, nothing is known about the generation and chemical behavior of arylbenzylnitrenium ions. Herein, we report that these species can be generated by a process involving an unprecedented therma
CYCLOADDITIONS WITH CAPTO-DATIVE OLEFINS, III ADDITION OF 2-MORPHOLINO-ACRYLONITRILE TO VARIOUS ALDONITRONES
Doepp, Dietrich,Walter, Jutta
, p. 1055 - 1061 (2007/10/02)
With very high regioselectivity, 2-morpholino-acrylonitrile (1) is added to aldonitrones to form unstable 5-morpholino-isoxazolidine-5-carbonitriles; the latter generally tend to form α,β-unsaturated carboxylic acid morpholides with ring opening and elimi
