872856-43-4Relevant academic research and scientific papers
Hybridized metal complex and application of hybridized metal complex in organic electrofluorescence device
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Paragraph 0005, (2019/06/27)
The invention discloses a hybridized metal complex electrophosphorescence compound. The organic metal electrofluorescence complex is composed of a main ligand with luminescence properties, a deuterated auxiliary ligand and metal, and the complex can be us
meta-C?H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis
Warratz, Svenja,Burns, David J.,Zhu, Cuiju,Korvorapun, Korkit,Rogge, Torben,Scholz, Julius,Jooss, Christian,Gelman, Dmitri,Ackermann, Lutz
supporting information, p. 1557 - 1560 (2017/02/05)
Methods for positionally selective remote C?H functionalizations are in high demand. Herein, we disclose the first heterogeneous ruthenium catalyst for meta-selective C?H functionalizations, which enabled remote halogenations with excellent site selectivity and ample scope. The versatile heterogeneous Ru@SiO2catalyst was broadly applicable and could be easily recovered and reused, which set the stage for the direct fluorescent labeling of purines. In contrast to palladium, rhodium, iridium, or cobalt complexes, solely the ruthenium catalysis manifold provided access to meta-halogenated purine derivatives, illustrating the unique power of ruthenium C?H activation catalysis.
Organometallic compound and organic light-emitting device including the same
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Paragraph 0314; 0339; 0340; 0341; 0342; 0343, (2016/10/07)
Organic metal compound and said organometallic compounds is disclosure is an organic light emitting device. (by machine translation)
Ruthenium-Catalyzed meta-Selective C-H Bromination
Teskey, Christopher J.,Lui, Andrew Y. W.,Greaney, Michael F.
supporting information, p. 11677 - 11680 (2015/10/05)
The first example of a transition-metal-catalyzed, meta-selective C-H bromination procedure is reported. In the presence of catalytic [{Ru(p-cymene)Cl2}2], tetrabutylammonium tribromide can be used to functionalize the meta C-H bond of 2-phenylpyridine derivatives, thus affording difficult to access products which are highly predisposed to further derivatization. We demonstrate this utility with one-pot bromination/arylation and bromination/alkenylation procedures to deliver meta-arylated and meta-alkenylated products, respectively, in a single step. Taking position: 2-Phenylpyridines undergo meta-selective bromination using tetrabutylammonium tribromide under ruthenium catalysis, thus affording products that are highly predisposed to further derivatization. The bromination can be combined with arylation and alkenylation chemistry to access meta-arylated and meta-alkenylated products, respectively, in a one-pot operation.
Organometallic complex, organometallic complex-containing composition, light-emitting material, organic electroluminescent element material, organic electroluminescent element, and an organic EL display EL lighting org.
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Paragraph 0151; 0152; 0154, (2018/12/01)
PROBLEM TO BE SOLVED: To provide organic metal complexes that can retain high performance in life, durability and the like of organic electroluminescent elements. SOLUTION: An iridium complex obtained from a 2-(3'-biphenyl)-pyridine derivative in which a pyridine group and/or a phenyl group at 3'-position has at least one ≥5C alkyl group as a substituent is provided. The iridium complex, for example, is an iridium complex D-3 synthesized by the reaction formula. COPYRIGHT: (C)2010,JPOandINPIT
Facile synthesis of cyclometalated ruthenium complexes with substituted phenylpyridines
Sasaki, Isabelle,Vendier, Laure,Sournia-Saquet, Alix,Lacroix, Pascal G.
, p. 3294 - 3302 (2007/10/03)
We have developed a new strategy that uses the Kroehnke synthesis for the preparation of various substituted phenylpyridines in excellent yields (up to 88%). Starting with the appropriate commercially available acetophenone, a variety of phenylpyridines substituted by either electron-donating (i.e. methyl, methoxy) or -withdrawing groups (i.e. bromide, nitro) on the phenyl ring are obtained in a two-step synthesis. The corresponding functionalized cyclometalated ruthenium complexes can be prepared with unusually high yields by using methanol as reaction solvent. The electrochemical data of the complexes demonstrate the strong σ-donating character of the anionic phenylpyridine ligand. X-ray analyses of four complexes show a shortening of the Ru-C bond associated with the elongation of only one of the five Ru-N bonds (trans effect). Wiley-VCH Verlag GmbH & Co, KGaA, 2006.
Electroluminescent efficiency
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, (2008/06/13)
An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further includes a molecule of Formula I wherein an alkyl substituent at position R′5 results in high efficiency and operational stability in the organic light emitting device.
